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- The newest dz2 and you can dx2-y2 orbitals lack because the head contact since the ligands sort of fit previous otherwise slip by the these types of orbitals, for this reason lowering the electron-electron repulsion plus the times of your orbital.
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Inside the equipment of your own quicker Planck lingering ħ, all dust you to relocate step 3 size have possibly integer spin and you may follow Bose-Einstein statistics otherwise 50 percent of-integer twist and you may follow Fermi-Dirac analytics. While the bromo ligand is actually a deep failing occupation ligand , which molecule is actually large twist. The fresh busting away from tetrahedral complexes is in person contrary regarding the new busting of one’s octahedral complexes. Recall one to inside the octahedral buildings, the brand new dz2 and you can dx2-y2 orbitals provides higher time compared to dxz, dxy, and you can dyz orbitals. Within the tetrahedral complexes, the exact opposite happens because the dxz, dxy, and you will dyz orbitals has higher energy versus dz2 and you can dx2-y2 orbitals.
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